Tiny correction. ML pretends to pass out on top of MC to test her and see what she'll do.
MC is never scared of ML. Before she meets him, based on what other people tell her, she thinks he's too weak to hurt anyone because of his serious injuries. She hopes that his reputation will keep her safe from her other demons and fiends. After she meets him, she see his wolf cub form then his giant wolf form. He tries a few things, but she misinterprets all his attempts. When she meets him, she's sleep deprived and physically exhausted, so I think her sense of danger is muted. And, it would be so easy, even just from one moment of carelessness, for him to hurt her, but that never happens, so she doesn't see him as a threat.
I agree with everything else.